The diffusion of ferro- and ferricyanide ions in aqueous solutions of sodium hydroxide

The diffusion of ferri- and ferrocyanide ions in sodium hydroxide solutions has been studied by means of a platinum rotating disk electrode. Results were obtained at variable concentrations an in the range of temperature between 24 and 40°C. The product Dɳ/T was approximately constant and independ...

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Detalles Bibliográficos
Autores principales: Bazán, Julio César, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1965
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/79976
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Sumario:The diffusion of ferri- and ferrocyanide ions in sodium hydroxide solutions has been studied by means of a platinum rotating disk electrode. Results were obtained at variable concentrations an in the range of temperature between 24 and 40°C. The product Dɳ/T was approximately constant and independent of temperature in the range studied. The dependence of D on the total ionic strength is mainly due to the change of viscosity at large ionic concentration.