A theoretical study of the thermal stability of the FS(O<SUB>2</SUB>)OSO<SUB>2</SUB> radical and the recombination kinetics with the FSO<SUB>3</SUB> radical

The kinetics of the thermal reaction of FS(O2)OO(O2)SF with SO2 have been theoretically studied. Experimental investigations performed at 293–323 K indicate that the FSO3 radical, in equilibrium with the peroxide FS(O2)OO(O2)SF ¢ 2 FSO3 (1, -1), initially attacks the SO2 forming the FS(O2)OSO2 radic...

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Detalles Bibliográficos
Autores principales: Badenes, María Paula, Cobos, Carlos Jorge, Croce, Adela Ester
Formato: Articulo
Lenguaje:Inglés
Publicado: 2018
Materias:
Química
FSO<SUB>3</SUB>, FS(O<SUB>2</SUB>)OSO<SUB>2</SUB>, (FS(O<SUB>2</SUB>)O)<SUB>2</SUB>SO<SUB>2</SUB>, quantum-chemical calculations, transition state theory, statistical adiabatic channel model
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/73218
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata

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