Solvent and substituent effects on the thermolysis of antimalarial fluorophenyl substituted 1,2.4-trioxanes

The kinetics and mechanism of the thermal decomposition reaction of <i>cis</i>-6-(4-fluoropheny1)-5,6-[2-(4-fluorophenyl)-propylidene]-3, 3-tetramethylene-1,2,4-trioxacyclo-hexane (I) were investigated separately in <i>n</i>-hexane and in methanol solutions over the temperatu...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Cafferata, Lázaro F. R., Rimada, Rubén S.
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	2003
Materias:	Ciencias Exactas Química alcohol oxidation antimalarial compounds chemical bond fluorophenyl substituted 1,2,4-trioxanes decomposition peroxides high temperature solvent and substituents effects temperature dependence thermal decomposition reactions thermal stimulation thermolysis
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/35017 http://www.mdpi.com/1420-3049/8/9/655
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

Ejemplares similares

Solvent and substituent effects on the kinetics of thermolysis of cis-fused 1,2,4-trioxanes
por: Cafferata, Lázaro F. R., et al.
Publicado: (2001)

A kinetic and mechanistic study on the thermal decomposition reactions of cis- and trans- fused 1,2,4-trioxanes
por: Cafferata, Lázaro F. R., et al.
Publicado: (2003)

Estabilidad térmica de 1, 2, 4-trioxanos: una nueva generación de antimaláricos
por: Jeandupeux, René, et al.
Publicado: (1995)

Thermal Behaviour of Pharmacologically Active Lithium Compounds
por: Tobón Zapata, Gloria Elena, et al.
Publicado: (2000)

Thermal decomposittion of the acetone cyclic diperoxide in 1-octanol solution
por: Leiva, L.C.A., et al.
Publicado: (2008)

Thermal decomposittion of the acetone cyclic diperoxide in 1-octanol solution
por: Leiva, L.C.A., et al.
Publicado: (2008)

Thermal decomposittion of the acetone cyclic diperoxide in 1-octanol solution
por: Leiva, L.C.A., et al.

Thermal decomposittion of the acetone cyclic diperoxide in 1-octanol solution
Publicado: (2008)

Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
por: Leiva, Laura A. C., et al.
Publicado: (2008)

Thermal stability of mixed-valent binuclear osmium (II, III) carboxylates
por: Fabiyi, F.A.S., et al.

Thermal stability of mixed-valent binuclear osmium (II, III) carboxylates
Publicado: (2010)

Synthesis of the SrFeO<SUB>2.5</SUB> and BaFeO<SUB>3-x</SUB> perovskites by thermal decomposition of SrNh<SUB>4</SUB>[Fe(Cn)<SUB>6</SUB>] 3H<SUB>2</SUB>O and BaNh<SUB>4</SUB>[Fe(Cn)<SUB>6</SUB>]
por: Córdoba, Lucrecia M., et al.
Publicado: (2008)

Shock wave and modelling study of the dissociation pathways of (C2F5)3N
por: Cobos, Carlos Jorge, et al.
Publicado: (2019)

Conformational equilibrium of the thermal unimolecular decomposition reactions of substituted 4-fluorophenyl 1,2,4-trioxanes
por: Cafferata, Lázaro F. R., et al.
Publicado: (2005)

Shock wave and modeling study of the thermal decomposition reactions of pentafluoroethane and 2-H-heptafluoropropane
por: Cobos, Carlos Jorge, et al.
Publicado: (2013)

Variability at low frequencies with wavelet transform and empirical mode decomposition: Aplication to climatological series
por: Zitto, M.E., et al.

Variability at low frequencies with wavelet transform and empirical mode decomposition: Aplication to climatological series
por: Zitto, Miguel Eduardo, et al.
Publicado: (2016)

Synthesis and structural characterization of perovskite YFeO3 by thermal decomposition of a cyano complex precursor, Y[Fe(CN)6]·4H2O
por: Gil, D.M., et al.
Publicado: (2010)

Proportion of oleic acid in olive oil as influenced by the dimensions of the daily temperature oscillation
por: García Inza, Georgina Paula

Proportion of oleic acid in olive oil as influenced by the dimensions of the daily temperature oscillation
por: García Inza, Georgina Paula

Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
por: Lick, Ileana Daniela, et al.
Publicado: (2009)

Kinetic study of benzyl sulfamide synthesis by thermolysis of N‐(benzyl)‐N´‐(tert butoxycarbolyl) sulfamide
por: Gavernet, Luciana, et al.
Publicado: (2013)

Low-temperature behaviour of elastomers
por: Bukhina, M. F. (Ma�i�a Faddeevna)
Publicado: (2007)

Thermal stability of mixed-valent diruthenium (II,III) carboxylates
por: Rusjan, M., et al.

Thermal stability of mixed-valent diruthenium (II,III) carboxylates
por: Rusjan, Marcia Cecilia, et al.
Publicado: (2003)

Kinetics and mechanism of thermal gas-phase oxidation of hexafluoropropene in the presence of trifluoromethylhypofluorite, CF3OF
por: Dos Santos Afonso, M., et al.

Kinetics and mechanism of thermal gas-phase oxidation of hexafluoropropene in the presence of trifluoromethylhypofluorite, CF3OF
Publicado: (2000)

Thermophysical properties : Eighth European Conference on Thermophysical Properties : Baden-Baden, FRG, 27 Sept.-1 Oct., 1982 /
Publicado: (1984)

Thermal decomposition reaction of cis-6-phenyl-5,6-(2-phenyl-propilydene)- 3,3-tetramethylene-1,2,4-trioxacyclohexane in different solvents
por: Cafferata, Lázaro F. R., et al.
Publicado: (2000)

Proceedings of the European Conference on High-Tc Thin Films and Single Crystals Sept. 30--Oct. 4, 1989, Ustrón, Poland /
Publicado: (1990)

Avances en el estudio teórico de la energética y degradación atmosférica de alquenos halogenados de interés medioambiental
por: Zucchini Cuevas, Paolo Giovanni
Publicado: (2022)

Thermal decomposition of mixed-valent diruthenium pentakis(alkanoates) enhanced by their liquid crystalline state
por: Rusjan, M.C., et al.

Thermal decomposition of mixed-valent diruthenium pentakis(alkanoates) enhanced by their liquid crystalline state
Publicado: (1999)

Evaluation of the thermal diffusivity of rubber compounds through the glass transition range
por: Camaño, E., et al.

Evaluation of the thermal diffusivity of rubber compounds through the glass transition range
Publicado: (1997)

Review of mesospheric temperature trends
por: Beig, G., et al.

Review of mesospheric temperature trends
Publicado: (2003)

Temperature effects on the immature development time of culex eduardoi casal & garcía (Diptera: Culicidae)
por: Loetti, V., et al.

Temperature effects on the immature development time of culex eduardoi casal & garcía (Diptera: Culicidae)
por: Schweigmann, Nicolás Joaquin, et al.
Publicado: (2011)

Variable thermal sensitivity as output of a circadian clock controlling the bimodal rhythm of temperature choice in the ant Camponotus mus
por: Roces, F.