Base hydrolysis and aquation of trans-methyl-substituted acidopenta-amminecobalt(III) complexes

Base hydrolysis and aquation of trans-[Co(NH₃)₄(NH₂CH₃)X]²⁺ (where X = Cl, Br and NO3) complexes are reported. Both types of reactions are four to eight times faster than the corresponding reactions for [Co(NH3)5X]2+ complexes. The positive activation entropies of the base hydrolysis for all the stu...

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Detalles Bibliográficos
Autores principales:	Benzo, Fabián, Massaferro, Adriana, Queirolo, Marcelo, Sienra, Beatriz, Capparelli, Alberto Luis, Mártire, Daniel Osvaldo
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	1996
Materias:	Química Base hydrolysis aquation reactions activation entropies
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/159209
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

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