Die IR-Spektren von Kobalt-, Nickel- und Zink-Orthovanadat

Infrared spectra of crystalline Co3(VO4)2, Ni3(VO4)2 and Zn3(VO4)2 as well as the laser-Raman spectrum of the last mentioned compound are reported and discussed. A series of solid solutions of the type (Zn/Ni)3(VO4)2 have also been prepared and investigated, in order to obtain a wider insight into t...

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Detalles Bibliográficos
Autores principales: Baran, Enrique José, Botto, Irma Lía, Ramos, Juan F., Aymonino, Pedro José
Formato: Articulo
Lenguaje:Alemán
Publicado: 1978
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/142081
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Sumario:Infrared spectra of crystalline Co3(VO4)2, Ni3(VO4)2 and Zn3(VO4)2 as well as the laser-Raman spectrum of the last mentioned compound are reported and discussed. A series of solid solutions of the type (Zn/Ni)3(VO4)2 have also been prepared and investigated, in order to obtain a wider insight into the spectroscopic behaviour of this class of compounds in the 500-250 cm−1 region. Comparisons with the formerly investigated isotypic Mg3(VO4)2 allows to confirm some of the earlier statements and assignments in the light of additional experimental information.