The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate

The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) A, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman s...

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Guardado en:
Detalles Bibliográficos
Autores principales: Piro, Oscar Enrique, Baran, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1997
Materias:
Física
Ciencias Exactas
Bis(malonato)oxovanadiumt(lV)
crystal structure
IR and Raman spectra
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/141107
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) A, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman spectra are also reported to attain a wider insight into the compound characteristics.

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