Hyperfine study of Cu3(ZrF 7)2·16H 2 O and its thermal decomposition

By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Ceolín, Marcelo Raúl, Taylor, Marcela Andrea, Martínez, Jorge Alberto
Formato: Articulo
Lenguaje:Inglés
Publicado: 1994
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/138244
Aporte de:
Descripción
Sumario:By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with angular correlation and gravimetric results.