A theoretical study of the rotational distribution of no resulting from dissociation of HNO

Nascent NO (X2ΠΩ=1/2, 3/2, v=0) rotational distributions following the unimolecular dissociation of HNO at 5 and 300 K have been calculated at excess energies from 5 to 500 cm−1, using the statistical adiabatic channel model on anab initio potential energy surface. The influence of the tunneling eff...

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Guardado en:
Detalles Bibliográficos
Autor principal: Cobos, Carlos Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1998
Materias:
Ciencias Exactas
Química
Unimolecular reactions
NO rotational distribution
HNO radical
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/135813
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:Nascent NO (X2ΠΩ=1/2, 3/2, v=0) rotational distributions following the unimolecular dissociation of HNO at 5 and 300 K have been calculated at excess energies from 5 to 500 cm−1, using the statistical adiabatic channel model on anab initio potential energy surface. The influence of the tunneling effect through the adiabatic channel barriers on the average rotational energies is investigated.

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