Infrared spectroscopic study of water in the hydrates of calcium nitroprusside: Ca[Fe(CN)5NO]·nH2O (n=1,4)

The infrared absorption bands due to the water molecules in calcium nitroprusside monohydrate and tetrahydrate were studied using partial deuteration and low-temperature techniques. An assignment of these bands based on the possible hydrogen bonds existing in the crystal lattice is proposed. Additio...

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Autores principales: Rigotti, Guillermo, Aymonino, Pedro José, Varetti, Eduardo Lelio
Formato: Articulo
Lenguaje:Inglés
Publicado: 1984
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/133609
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Sumario:The infrared absorption bands due to the water molecules in calcium nitroprusside monohydrate and tetrahydrate were studied using partial deuteration and low-temperature techniques. An assignment of these bands based on the possible hydrogen bonds existing in the crystal lattice is proposed. Additional infrared spectroscopic data on the monohydrate and the anhydrous compound are included.