A serendipitous one-step conversion of 3H-1,2-dithiole-3-thione to (E)-3-(1-(alkylthio)alkylidene)-3H-1,2-dithiole: an experimental and theoretical study
In the course of our studies on 3H-1,2-dithiole-3-thione synthesis, a serendipitous reactivity with α-haloketones, in the presence of excess of potassium iodide, has been observed. Instead of the expected reaction of the nucleophile in a remote point of the molecule, we have obtained a product resul...
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| Autores principales: | Couto, Marcos, Cabrera, Mauricio, Echeverría, Gustavo Alberto, Piro, Oscar Enrique, González, Mercedes, Cerecetto, Hugo |
|---|---|
| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2014
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/133530 |
| Aporte de: |
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