A SACM study of the cross-combination ratio of rate constants

An analysis of the cross-combination ratio of the rate constants ϕ in terms of the statistical adiabatic channel model allows to factorize ϕ into two contributions: one due to the motion along the reaction coordinates and another due to the reaction transitional modes. ϕ for the CH3/CCl3, CH3/C2H3,...

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Guardado en:
Detalles Bibliográficos
Autor principal: Cobos, Carlos Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1993
Materias:
Ciencias Exactas
Física
ratio of rate constants
statistical adiabatic channel model
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/132777
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:An analysis of the cross-combination ratio of the rate constants ϕ in terms of the statistical adiabatic channel model allows to factorize ϕ into two contributions: one due to the motion along the reaction coordinates and another due to the reaction transitional modes. ϕ for the CH3/CCl3, CH3/C2H3, CH3/C3H5, CH3/C2H5 and C2H5/C3H5 radical pairs were calculated.

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