A chemical-physics test for nonextensivity in thermodynamics

An ideal mixture of parahydrogen (with nuclear spin K=0) and orthohydrogen (with K=1), in statistical weights 1/4 and 3/4, respectively, is used as a test ground for the existence of non-extensivity in chemical physics. We report on a new bound on the non extensivity parameter q - 1 that characteriz...

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Autores principales: Di Sisto, Romina Paula, Martínez, S., Pennini, Flavia, Plastino, Ángel Luis, Vucetich, Héctor
Formato: Articulo
Lenguaje:Inglés
Publicado: 2002
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/132126
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Sumario:An ideal mixture of parahydrogen (with nuclear spin K=0) and orthohydrogen (with K=1), in statistical weights 1/4 and 3/4, respectively, is used as a test ground for the existence of non-extensivity in chemical physics. We report on a new bound on the non extensivity parameter q - 1 that characterizes generalized thermostatistics a la Tsallis. This bound is obtained on the basis of laboratory measurements of the specific heat of hydrogen. Suggestions are advanced for the performance of improved measurements.