Redox mediation at poly(o-aminophenol) coated electrodes: mechanistic diagnosis from steady state polarization curves
In this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to re...
Guardado en:
| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/128505 |
| Aporte de: |
| Sumario: | In this work, the mediated reduction and oxidation of Fe(CN) 6 3-/4- and Fe 3+ in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements. |
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