Determination of the blocking temperature of magnetic nanoparticles : The good, the bad, and the ugly

A numerically solved two-level Stoner-Wohlfarth model with thermal agitation is used to simulate Zero Field Cooling (ZFC)–Field Cooling (FC) curves of monosize and polysize samples and to determine the best method for obtaining a representative blocking temperature T<sub>B</sub> value of...

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Autores principales: Bruvera, Ignacio Javier, Mendoza Zélis, Pedro, Calatayud, M. Pilar, Goya, Gerardo Fabián, Sánchez, Francisco Homero
Formato: Articulo
Lenguaje:Inglés
Publicado: 2015
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/124066
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Sumario:A numerically solved two-level Stoner-Wohlfarth model with thermal agitation is used to simulate Zero Field Cooling (ZFC)–Field Cooling (FC) curves of monosize and polysize samples and to determine the best method for obtaining a representative blocking temperature T<sub>B</sub> value of polysize samples. The results confirm a technique based on the T derivative of the difference between ZFC and FC curves proposed by Micha et al. (the good) and demonstrate its relation with two alternative methods: the ZFC maximum (the bad) and the inflection point (the ugly). The derivative method is then applied to experimental data, obtaining the T<sub>B</sub> distribution of a polysize Fe<sub>3</sub>O<sub>4</sub> nanoparticle sample suspended in hexane with an excellent agreement with TEM characterization.