Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reactio...
Guardado en:
| Autores principales: | , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1973
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119948 https://www.sciencedirect.com/science/article/abs/pii/0013468673800775 |
| Aporte de: |
| Sumario: | The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step. |
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