Electrochemical oxidation of iodide dissolved in sodium-nitrate-potassium-nitrate eutectic melt on a platinum rotating disk electrode

The E/I curve related to the electrochemical oxidation of iodide dissolved in molten nitrates on a platinum rotating disk electrode involves two anodic waves. The first corresponds to a reversible two-electron process and the second to a reversible one-electron process. A definite ratio between the...

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Autores principales: Triaca, Walter Enrique, Videla, Héctor A., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1971
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119491
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Sumario:The E/I curve related to the electrochemical oxidation of iodide dissolved in molten nitrates on a platinum rotating disk electrode involves two anodic waves. The first corresponds to a reversible two-electron process and the second to a reversible one-electron process. A definite ratio between the anodic limiting currents is established suggesting that the second anodic wave is not independent from the first one. The parameters related to the diffusion of the species participating in the reaction are evaluated.