Infrared absorption spectra of bis(monofluorocarbonyl) and bis(trifluoromethyl)-peroxides

Infrared absorption spectra of gaseous (FCO)<sub>2</sub>O<sub>2</sub> and (F<sub>3</sub>C)<sub>2</sub>O<sub>2</sub> have been obtained in the NaCl and KBr regions. By comparison with the spectra of F<sub>2</sub>CO and F<sub&g...

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Detalles Bibliográficos
Autores principales: Arvia, Alejandro Jorge, Aymonino, Pedro José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1962
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/118216
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Sumario:Infrared absorption spectra of gaseous (FCO)<sub>2</sub>O<sub>2</sub> and (F<sub>3</sub>C)<sub>2</sub>O<sub>2</sub> have been obtained in the NaCl and KBr regions. By comparison with the spectra of F<sub>2</sub>CO and F<sub>3</sub>COF, most of the bands related to fundamental vibration modes of the molecules of both peroxides have been identified. Results agree with the structure previously postulated for both substances.