Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup>

An isolated reaction intermediate in the desulfurization of thiones promoted by phosphanes is provided by the ylide derivative 3, which is obtained by thiophilic addition of PCy<sub>3</sub> to 2. Complex 2 is formed from the disulfide‐containing dimetallic complex 1 by scission of the S−...

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Guardado en:
Detalles Bibliográficos
Autores principales: Ruiz, Javier, Ceroni, Mario, Quinzani, Oscar Valentín, Riera, Víctor, Piro, Oscar Enrique
Formato: Articulo Comunicacion
Lenguaje:Inglés
Publicado: 2001
Materias:
Ciencias Exactas
Física
Química
manganese
phosphanes
sulfur
ylides
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/104400
http://hdl.handle.net/11336/98686
https://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20010105)40:1%3C220::AID-ANIE220%3E3.0.CO;2-3
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:An isolated reaction intermediate in the desulfurization of thiones promoted by phosphanes is provided by the ylide derivative 3, which is obtained by thiophilic addition of PCy<sub>3</sub> to 2. Complex 2 is formed from the disulfide‐containing dimetallic complex 1 by scission of the S−S bond. [Mn]=Mn(CO)<sub>4</sub>⁺, R=Ph.

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