Experimental and theoretical investigation of the enantioselective hydrogenation of ethyl pyruvate with a Pt catalyst with new non-cinchona chiral modifiers

The enantioselective hydrogenation of ethyl pyruvate using a Pt/SiO2 catalyst modified with six different chiral modifiers was studied. The chiral modifiers chosen were: (S)-(+)-1-aminoindan, (R)-(−)-1-aminoindan, (1R,2S)-(+)-cis-1- amino-2-indanol, (1S,2R)-(−)-cis-1-amino-2-indanol, (S)-(+)-1-indan...

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Detalles Bibliográficos
Autores principales: Ruggera, José Fernando, Merlo, Andrea Beatriz, Pis Diez, Reinaldo, Casella, Mónica Laura
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2016
Materias:
Química
Enantioselectivity
Ethyl pyruvate
Non-cinchona modifiers
Dft
Platinum
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/104243
http://hdl.handle.net/11336/41639
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata

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