Fotofísica y fotoquímica de compuestos de coordinación: interacción con proteínas pequeñas y estudios básicos de transferencia de electrones
Metal complexes of the third transition series of tricarbonyl Re (I) coordinated mono or bidentate azines, general formula fac-XRE (CO) 3L (where X = halide and /or substituted azine and L2 = bidentate azine and fac indicates that the three carbonyls are in the same face of the octahedron) show an e...
Guardado en:
| Autores principales: | , |
|---|---|
| Formato: | Articulo |
| Lenguaje: | Español |
| Publicado: |
2013
|
| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/100016 https://ri.conicet.gov.ar/11336/24377 https://www.aqa.org.ar/images/anales/pdf100/art15.pdf |
| Aporte de: |
| Sumario: | Metal complexes of the third transition series of tricarbonyl Re (I) coordinated mono or bidentate azines, general formula fac-XRE (CO) 3L (where X = halide and /or substituted azine and L2 = bidentate azine and fac indicates that the three carbonyls are in the same face of the octahedron) show an extraordinarily rich behavior in their excited states at their redox reactions, as well as good thermal stability and fotochemistry [1]. Because of this have attracted great interest recent research in the field of coordination compounds. It can vary widely spectroscopic, photophysical, photochemical and electrochemical properties of Re chromophore when using different ligands L and X in the synthesis of these complexes. In order to tune the photophysical and photochemical properties of these metal complexes, a rational design azines bidentate ligands has been development, so they can be used in studies of electron transfer reactions [2] solar energy conversion [3-5] and technological implementation studies for catalytic processes [6]. It has recently become possible to use these compounds in the luminescent sensor design, [7-9] as materials for non-lineal optical [10-11] and as optical switches [12]. |
|---|