New chiral 1,2-aminoalcohols derived from biomass and their application in diethyl zinc additions

A convenient procedure for the preparation of chiral 1,2-aminoalcohols starting from levoglucosenone, a biomass derivative, is described. The 1,2-aminoalcohols, bearing primary, secondary, and tertiary amino groups, were tested as chiral catalysts in the asymmetric addition of diethyl zinc to benzal...

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Autores principales: Zanardi, María Marta, Botta, María Celeste, Suárez, Alejandra Graciela
Formato: article artículo publishedVersion
Lenguaje:Inglés
Publicado: Elsevier 2019
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Acceso en línea:http://hdl.handle.net/2133/13891
http://hdl.handle.net/2133/13891
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Sumario:A convenient procedure for the preparation of chiral 1,2-aminoalcohols starting from levoglucosenone, a biomass derivative, is described. The 1,2-aminoalcohols, bearing primary, secondary, and tertiary amino groups, were tested as chiral catalysts in the asymmetric addition of diethyl zinc to benzaldehyde.