A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles

The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylen...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autor principal: Edelsztein, V.C
Otros Autores: Jares-Erijman, E.A, Müllen, K., Di Chenna, P.H, Spagnuolo, C.C
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2012
Acceso en línea:Registro en Scopus
DOI
Handle
Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
Descripción
Sumario:The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylene fluorophore. The compatibility of the photochromic compound in this medium and the non-destructive readout capability were demonstrated. The dye doped organogel was further used as a template and an innovative method was employed to grow fluorescent silica spherical nanoparticles with physically and chemically admixed perylene dye. © 2012 The Royal Society of Chemistry.
Bibliografía:Das, D., Kar, T., Das, P.K., (2012) Soft Matter, 8, p. 2348
Steed, J.W., (2011) Chem. Commun., 47, p. 1379
Ajayaghosh, A., Praveen, V.K., Vijayakumar, C., (2008) Chem. Soc. Rev., 37, p. 109
Huebon, F.J.M., Jonkheijim, P., Meijer, E.W., Schenning, A.P.H.J., (2005) Chem. Soc. Rev., 105, p. 1491
Li, X., Peng, J., Kang, J., Choy, J., Steinhart, M., Knoll, W., Kim, D., (2008) Soft Matter, 4, p. 515
Sada, K., Takeuchi, M., Fujita, N., Numata, M., Shinkai, S., (2007) Chem. Soc. Rev., p. 415
Yagai, S., Ishii, M., Karatsu, T., Kitamura, A., (2007) Angew. Chem., Int. Ed., 46, p. 1
Huang, X., Weiss, R.G., (2007) Tetrahedron, 63, p. 7375
Kawano, S., Fujita, N., Shinkai, S., (2003) Chem. Commun., p. 1352
Llusar, M., Sanchez, C., (2008) Chem. Mater., 20, p. 782
Sugiyasu, K., Fujita, N., Shinkai, S., (2004) Angew. Chem., Int. Ed., 43, p. 1229
Edelsztein, V.C., Burton, G., Di Chenna, P.H., (2010) Tetrahedron, 66, p. 2162
Weil, T., Vosch, T., Hofkens, J., Peneva, K., Müllen, K., (2010) Angew. Chem., Int. Ed., 49, p. 2
Inokuchi, H., (1988) Angew. Chem., Int. Ed. Engl., 27, p. 1747
Li, C., Schöneboom, J., Liu, Z., Pschirer, N.G., Erk, P., Herrmann, A., Müllen, K., (2009) Chem.-Eur. J., 15, p. 878
Peneva, K., Mihov, G., Nolde, F., Rocha, S., Hotta, J.-I., Braeckmans, K., Hofkens, J., Müllen, K., (2008) Angew. Chem., Int. Ed., 47, p. 3372
Würthner, F., Hanke, B., Lysetska, M., Lambright, G., Harms, G.S., (2005) Org. Lett., 7, p. 967
Wu, H., Xue, L., Shi, Y., Chen, Y., Li, X., (2011) Langmuir, 27, pp. 3074-3082
Brome, W.R., De Jong, J.J.D., Kudernac, T., Walko, M., Lucus, L.M., Uchida, K., Van Esch, J.H., Feringa, B.L., (2005) Chem.-Eur. J., 11, p. 6414
Irie, M., (2000) Chem. Rev., 100, p. 1685
Tsivgoulis, G.M., Lehn, J.-M., (1996) Chem.-Eur. J., 1, p. 285
Fukaminato, T., Sasaki, T., Kawai, T., Tamai, T., Irie, M., (2004) J. Am. Chem. Soc., 126, p. 14843
Giordano, L., Jovin, T.M., Irie, M., Jares-Erijman, E.A., (2002) J. Am. Chem. Soc., 124, p. 7481
Matsuda, K., Irie, M., (2004) J. Photochem. Photobiol., C, 5, p. 169
Raymo, F.M., Tomasulo, M., (2005) J. Phys. Chem. A, 109, p. 7343
Tian, H., Yang, S., (2004) Chem. Soc. Rev., 33, p. 85
Kobatake, S., Yamada, M., Yamada, T., Irie, M., (1999) J. Am. Chem. Soc., 121, p. 8450
Bae, S.W., Tan, W., Hong, J., (2012) Chem. Commun., 48, p. 2270
Chung, J.W., Yoon, S., Lim, S., An, B., Park, S.Y., (2009) Angew. Chem., Int. Ed., 48, p. 7030
Schneider, M., Mu, K., (2000) Chem. Mater., 12, p. 352
ISSN:09599428
DOI:10.1039/c2jm34891h