Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The result...
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1976
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 04656caa a22006497a 4500 | ||
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| 001 | PAPER-18672 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205002.0 | ||
| 008 | 190411s1976 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-2142722236 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Nudelman, N.S. | |
| 245 | 1 | 0 | |a Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| 260 | |c 1976 | ||
| 270 | 1 | 0 | |m Nudelman, N.S.; Dep. de Química Orgánica, Facultad de Cs. Exactas y Naturales, Ciudad Universitaria, Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
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| 504 | |a Brewis, D.M., Chapman, N.B., Paine, J.S., Shorter, J., Wright, D.J., (1974) J.C.S. Perkin II, p. 1787 | ||
| 504 | |a Timmermans, J., Roland, H., (1959) J. chim. Phys, 56, p. 984 | ||
| 504 | |a Nudelman, N.S., Brieux, J.A., (1970) Anales A soc. quim. Argentina, 58, p. 207 | ||
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| 504 | |a Kost, A.N., Terent’ev, A.P., Shvekhgeimer, G.A., (1951) Izvest. Akad. Nauk S.S.S.R., Otdel. Khim. Nauk, p. 150 | ||
| 504 | |a Kost, A.N., Terent’ev, A.P., Shvekhgeimer, G.A., (1951) Chem. Abs, 45. , 10195c | ||
| 504 | |a Vogel, A.I., (1956) Practical Organic Chemistry, 168p. , Longman, London, 3rd edn | ||
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| 504 | |a Bunnett, J.F., Kato, T., Nudelman, N.S., Fundamental Organic Chemistry Laboratory Manual, 112p. , K. Thomas Finley and J. Wilson, Prentice Hall, New Jersey | ||
| 504 | |a Bernasconi, C.F., (1973) M.T.P. International Rev. Sci. Org. Chem. Ser. 1, 3, p. 33 | ||
| 504 | |a Bunnett, J.F., Bernasconi, C.F., (1970) J. Org. Chem, 35, p. 70 | ||
| 504 | |a N. S. Nudelman and J. A. Brieux, unpublished results; Bunnett, J.F., Morath, R.J., (1955) J. Amer. Chem. Soc, 77, p. 5051 | ||
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| 504 | |a Gurney, R.W., (1953) Ionic Processes in Solution, p. 122. , Dover, New York | ||
| 504 | |a Bunnett, J.F., (1974) Techniques of Chemistry, 6, 406p. , E. S. Lewis, Wiley, New York, ch. VIII | ||
| 504 | |a Bunnett, J.F., Kato, T., Nudelman, N.S., (1969) J. Org. Chem, 34, p. 785 | ||
| 520 | 3 | |a The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate. |l eng | |
| 593 | |a Dep. de Química Orgánica, Facultad de Cs. Exactas y Naturales, Ciudad Universitaria, Buenos Aires, Argentina | ||
| 700 | 1 | |a Garrido, D. | |
| 773 | 0 | |d 1976 |h pp. 1256-1260 |k n. 11 |x 1472779X |t Journal of the Chemical Society, Perkin Transactions 2 | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-2142722236&doi=10.1039%2fP29760001256&partnerID=40&md5=9555cf501488fef732d8046606aaf654 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1039/P29760001256 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n11_p1256_Nudelman |y Registro en la Biblioteca Digital |
| 961 | |a paper_1472779X_v_n11_p1256_Nudelman |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 79625 | ||