Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene
The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation...
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| Otros Autores: | , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1962
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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